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京ICP备15050585号河北祥鹄科学仪器有限公司
Synthesis of a novel two-dimensional BINOL metal-organic framework
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[Abstract]:
The ligand 1,1-binaphthyl-2,2-dihydroxy-6,6-dicarboxylic acid was prepared by esterification, coupling and hydrolysis with 2-hydroxy-6-naphthoic acid as raw material, and synthesized by diffusion method. A new two-dimensional BINOL-Sr metal organic framework (MOF). The introduction of catalytically active chiral molecules BINOL, Schiff base, metalloporphyrin and other compounds into the framework of MOFs is an effective strategy for the design and synthesis of heterogeneous asymmetric catalysts and chiral separation.
